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allyl
(redirected from allyl radical)

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allyl

In chemistry, the propenyl group, an unsaturated organic radical corresponding to the formula CH2:CHCH2.

The chief compounds are allyl alcohol (propenol), with the general properties of a primary alcohol; allyl iodide, a colourless liquid with an odour of garlic; allyl bromide, a heavy liquid obtained by treating allyl alcohol with phosphorus tribromide; allyl sulphide, or ‘oil of garlic’, obtained by macerating garlic; and allyl isothiocyanate, or ‘oil of mustard’, occurring in black mustard seeds.



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? Mentioned in ? References in periodicals archive
 
However, the unsaturation generated by radical--radical disproportionation can also support crosslinking [12, 13] if it engages in radical addition, or if it results in the formation of allyl radicals that have a limited capacity for monomer addition and a pronounced preference for termination by combination [14].
Comparative analysis of radical-mediated polyethylene modifications: ... by Sengupta, Saurav S.; Parent, J. Scott / Polymer Engineering and Science
Oxidation of the allyl radical of thymine yields 5-hydroxymethyluracil (5-OHMUra).
Reactive oxygen species: from DNA damage to disease by Cooke, Marcus S.; Evans, Mark D. / Science & Medicine
The allyl radical in polybutadiene does not have such protection and basically undergoes a free
Rubber degradation and stabilization by Kuczkowski, Joseph A. / Rubber World
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