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ligand
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The presence of a bulky bidentate polar modifier at the chain end may decrease linking efficiencies, similar in effect to the presence of sterically hindered monomer units at the chain terminus (ref. 160 LEUTENEGGER U,TETRAHEDRON,vol 0048,page 2143,1992,cites= 27,5 -AZA-SEMICORRINS - A NEW CLASS OF BIDENTATE NITROGEN LIGANDS FOR ENANTIOSELECTIVE CATALYSIS In the case of MDI foams, it seems that the covalent network is of good quality even at high water/low MDI indices; however, the virtual network, consisting of the hard segments, is very weak as reflected by the high swelling and nonexistent bidentate carbonyl links (determined by FTIR). |
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