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boron |
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boronNon-metallic element, atomic number 5, relative atomic mass 10.811. In nature it is found only in compounds, as with sodium and oxygen in borax. It exists in two allotropic forms (see allotropy): brown amorphous powder and very hard, brilliant crystals. Its compounds are used in the preparation of boric acid, water softeners, soaps, enamels, glass, and pottery glazes. In alloys it is used to harden steel. Because it absorbs slow neutrons, it is used to make boron carbide control rods for nuclear reactors. It is a necessary trace element in the human diet. The element was named by Humphry Davy, who isolated it in 1808, from borax + -on, as in carbon. Boron
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D-Glucaric acid was measured by high-performance liquid chromatography with an ultraviolet detector after pretreatment of urine with boronic acid gel to remove interfering substances such as L-ascorbic acid and D-glucuronic acid (Pooh et al. The hydroxylated PCBs were synthesized using the Suzuki coupling of chlorobenzene boronic acids with bromochloro anisoles followed by demethylation with boron tribromide. Over 40,000 products are listed including boronic acids and esters, heterogeneous catalysts, advanced chiral intermediates, and MOCVD precursors. |
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